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Vasudevan and Sundararajan synthesized a new tri-block copolymer polyglycidylazide-b-polybutadiene-b-pol-yglycidylazide (GAP-PB-GAP) by cationic ring opening polymerization of epichlorohydrin (ECH) with HTPB as the initiator and boron trifluoride dietherate as the catalyst followed by azidation (7).
An ion exchange resing (A-15) with an end-capper are used to control the molecular weight of the ring opening polymerization to form linear siloxanes.
OMe]], (Ln = Sm, Yb) have been synthesized as potential precatalysts for the ring opening polymerization of LA.
This study, however, focuses on a three-step reaction involving ring opening polymerization and melt chain extending reaction to synthesize multiblock poly(ester-urethane).
The mechanism of polymerization is similar to conventional ring opening polymerization, with initiation and propagation steps.
ring opening polymerization versus condensation polymerization plays a crucial role in determining the microstructures of the resulting polymers.
 have conducted extensive studies in the ring opening polymerization (ROP) of various monomers.
It is apparently caused by the acidic catalysis of octadecylammonium ions on epoxy ring opening polymerization also observed in Fig.