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In the new study, Mosier-Boss and colleagues inserted an electrode composed of nickel or gold wire into a solution of palladium chloride mixed with deuterium or "heavy water" in a process called co-deposition.
For example, complexation of di-tert-butylneopentylphosphine with allyl palladium chloride dimer resulted in the allyl palladium chloride phosphine adduct, which shows substantial activity in Hartwig-Buchwald amination.
The activator is a colloidal catalytic solution formed by the admixture of palladium chloride salts, a stannous salt in molar excess of the catalytic metal salt (palladium) all in an acidic medium.